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2 article(s) from Gibb, Bruce C.

Dynamic light scattering studies of the effects of salts on the diffusivity of cationic and anionic cavitands

Anthony Wishard and
Bruce C. Gibb

Beilstein J. Org. Chem. 2018, 14, 2212–2219, doi:10.3762/bjoc.14.195

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Graphical Abstract

Figure 1: Chemical structures of octaacid 1 and positand 2 showing the anionic binding sites of the two hosts...

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Figure 2: Representative plots of the volume-weighted distribution obtained by DLS for salts titrated into 2....

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Figure 3: Representative plots of the volume-weighted distribution obtained by DLS for salts titrated into 2....

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Scheme 1: Visualization of the competitive equilibrium between iodide binding to host 2 or associating with i...

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Full Research Paper

Published 23 Aug 2018

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From steroids to aqueous supramolecular chemistry: an autobiographical career review

Bruce C. Gibb

Beilstein J. Org. Chem. 2016, 12, 684–701, doi:10.3762/bjoc.12.69

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Scheme 1: The formation of a 1:1 complex and a 2:1 supramolecular nano-capsule complex from bowl-shaped “cavi...

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Scheme 2: Abbreviated synthesis of 7-amino-2-phenyl-6-azaindolizine.

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Figure 1: My two favorite compounds for my Ph.D. dissertation, “The Synthesis and Structural Examination of 3...

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Scheme 3: An inspiring chlorination from the group of Ronald Breslow.

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Scheme 4: The carceplex reaction.

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Figure 2: Schematic of a cavitein.

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Figure 3: General structure of zinc-TPA complexes.

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Scheme 5: Stereoselective bridging of a resorcinarene with benzal halides.

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Scheme 6: An eight-fold Ullman ether “weaving” reaction.

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Scheme 7: Directed ortho-metallation of the deep-cavity cavitands, showing the mono-endo substituted to tetra-...

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Scheme 8: Macrocycle synthesis via resorcinarene covalent templates.

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Figure 4: Tris-pyridyl hosts.

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Figure 5: (Center) Chemical structure of the octa-acid host. (Left and right) Respective space-filling repres...

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Figure 6: Cartoons of the 2:1 host–guest complexes of estradiol (left) and cholesterol (right).

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Figure 7: Representative guests for the capsular complexes formed by octa-acid (stoichiometry shown in parent...

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Figure 8: A dendrimer-coated cavitand.

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Figure 9: Selective oxidation of olefins by singlet oxygen.

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Figure 10: a) Preferred packing motifs of methyl, pentyl and octyl guests. b) Product distribution observed fo...

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Figure 11: Schematic of the competition of two esters for the capsule formed by octa-acid. The ester that bind...

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Figure 12: Schematic of the inter-phase separation of propane and butane; the latter binds more strongly to th...

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Figure 13: Structure of tetra-endo-methyl octa-acid (TEMOA).

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Figure 14: Assembly properties of TEMOA.

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Figure 15: How salts influence the association constant (K_a) for the binding of ClO₄^– to octa-acid (Figure 4). The ind...

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Published 12 Apr 2016

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